Since nvidia 535.x and new Steam GUI windows might not spawn and you have trouble using it. Here are ways to solve this:
$ steam -vgui launches Steam with partly old UI. Should work, but can't use friends network and if opening game properties webview will crash and reset.
I also had problems today with Steam but with a different solution. I had to remove the xdg-desktop-portal-gnome to get any window to show up for Steam