I used NixOS for a couple of years. My experience is like this:
It is a rolling release (mostly)
You write a declarative configuration for your system, e.g., my config will say I want Neovim with certain plugins, and I can also include my Neovim configuration
It is stable, and when it breaks it is easy to go back
Yes absolutely. It is really great. It is also a source of frustration, e.g., missing configuration options, non-obvious options and so on. Overall it works well.
You can even define configurations for different systems/hosts/users from a single place. I'ev atomized my config and I can reuse lots of parts for my different machines. Also my user config is nearly identical (except hardware specific things).
Are you still using it and happy with it? I've been increasingly setting single purpose dev VMs in server, and a declarative configuration system would make the process of spinning them up faster and more robust. My current shell script system is clunky, and I've been looking at Ansible.